PM10 concs in UK section 6
6 PM10 Projections for roadside monitoring sites
The receptor modelling methods have been extended to calculate projections for 1997 of roadside PM10 concentrations for comparison with the NAQS objective and EU limit values. We have used daily measurements of PM10 at the roadside along with rural sulphate values and measurements of NOx at the roadside and at a nearby urban background monitoring site. A regression analysis has been carried out to find the coefficients A, B and R:
- = A.Background NOx + B.Sulphate + R.Roadside enhancement of NO
x + C
Where the Roadside enhancement of NOx is defined as the measured daily mean NOx concentration at the roadside site with a background daily mean NOx concentration from a nearby background site subtracted:
roadside enhancement concentration = roadside concentration - background concentration
The regression coefficients and correlation coefficients obtained from this analysis are listed in Table 6.1.
Table 6.1 Coefficients of regression analysis of roadside sites (NOx expressed as ppb)
|
Sulphate |
Background NOx |
Roadside NOx |
Intercept |
r2 |
London A3 |
2.74 |
0.177 |
0.0423 |
6.43 |
0.74 |
Bury Roadside |
2.64 |
0.138 |
0.0662 |
6.90 |
0.71 |
Camden Roadside |
2.33 |
0.120 |
0.0696 |
11.2 |
0.77 |
Haringey Roadside |
2.53 |
0.125 |
0.0776 |
7.90 |
0.80 |
Glasgow Kerbside |
3.11 |
0.0689 |
0.1234 |
6.92 |
0.79 |
London Hillingdon |
2.42 |
0.135 |
0.0748 |
5.60 |
0.78 |
Marylebone Road |
3.26 |
0.122 |
0.0901 |
6.12 |
0.79 |
Sutton Roadside |
2.40 |
0.110 |
0.0961 |
7.04 |
0.74 |
We have then calculated projections for 2004 and 2005 and 2009 using the business as usual scenario. We have assumed that the roadside enhancement of PM10 consists of 50% fine exhaust emissions and 50% coarse resuspended dust. This is consistent with a comparison of the roadside enhancements of PM10, PM2.5 and NOx at Marylebone Road carried out by APEG (APEG 1998). Figure 6.1 shows that the slope of the regression line between the roadside enhancement of particle concentration and the roadside enhancement of NOx for PM10 is twice the slope for PM2.5. The exhaust emissions are asumed to reduce in line with projected urban traffic emissions and the coarse resuspended dust is assumed to remain at 1997 levels.
The resulting projections are shown in Table 6.2. All sites are projected to exceed the NAQS objective in 2005 and the EU Stage 2 2009 98th percentile. Four of the sites are projected to exceed the EU 24-hour limit value in 2004, with three other sites having concentrations close to 50 mgm-3. At Marylebone Road the projected annual mean in 2004 is higher than the annual limit value of 40 mgm-3.
Table 6.2. PM10 projections for Roadside sites based on 1997 monitoring data (mgm-3).
NAQS |
London A3 Roadside |
Bury Roadside |
Camden Roadside |
Haringey Roadside |
Glasgow Kerbside |
London Hillingdon |
Marylebone Road |
Sutton Roadside |
1997 annual mean |
28 |
30 |
32 |
26 |
31 |
25 |
39 |
24 |
1997 99th percentile |
68 |
79 |
91 |
87 |
81 |
85 |
99 |
78 |
1997 Days>=50 |
7 |
14 |
32 |
19 |
19 |
15 |
26 |
16 |
Est. An. Mean 2004 |
24 |
25 |
28 |
23 |
26 |
22 |
32 |
21 |
Est. An. Mean 2005 |
23 |
25 |
28 |
22 |
26 |
21 |
32 |
21 |
Est. An. Mean 2009 |
21 |
23 |
26 |
21 |
24 |
19 |
29 |
19 |
99th perc. 2005 |
58 |
66 |
73 |
70 |
71 |
70 |
76 |
60 |
99th perc. 2009 |
53 |
61 |
68 |
64 |
68 |
65 |
68 |
58 |
2005 Days>=50 |
1 |
6 |
17 |
9 |
10 |
7 |
14 |
7 |
2009 Days>=50 |
0 |
5 |
13 |
7 |
3 |
6 |
10 |
3 |
EU |
1997 annual mean |
36 |
39 |
42 |
34 |
40 |
33 |
51 |
31 |
1997 90th percentile |
57 |
61 |
62 |
55 |
61 |
54 |
76 |
49 |
1997 98th percentile |
70 |
80 |
96 |
81 |
81 |
77 |
103 |
74 |
1997 Days>=50 |
25 |
47 |
83 |
51 |
74 |
50 |
66 |
34 |
Est. An. Mean 2004 |
31 |
33 |
36 |
30 |
34 |
29 |
42 |
27 |
Est. An. Mean 2009 |
27 |
30 |
34 |
27 |
31 |
25 |
38 |
25 |
2004 90th percentile |
48 |
51 |
54 |
47 |
52 |
45 |
65 |
43 |
2009 90th percentile |
60 |
46 |
50 |
43 |
48 |
41 |
59 |
38 |
2004 98th percentile |
43 |
69 |
80 |
66 |
69 |
65 |
81 |
65 |
2009 98th percentile |
55 |
62 |
73 |
62 |
64 |
61 |
72 |
58 |
2004 Days>=50 |
12 |
27 |
46 |
25 |
36 |
20 |
37 |
22 |
2009 Days>=50 |
6 |
18 |
36 |
22 |
20 |
14 |
20 |
15 |